Adsorptive Removal of Nitrogen and Sulfur Containing Compounds by SBA15 Supported Nickel (II) and Tungsten Phosphides and the Adsorption Mechanisms

摘要

SBA15 supported transition metal phosphides Ni2P/SBA15 and WP/SBA15 have been identified as promising adsorbents especially for removing neutral nitrogen-containing compounds. Adsorption of model nitrogen- and sulfur-containing compounds as well as light cycled oil (LCO) was performed and applied for the evaluation of kinetics and isotherms. The pseudo second-order kinetic model was well fitted to both nitrogen and sulfur adsorption data. Molecular size of the adsorbates plays an important role in the adsorption. Despite of higher initial adsorption rates, the adsorption capacities for carbazole and DBT were lower than those for indole and quinoline due to their larger molecular size. Monolayer adsorption was observed for quinoline due to the acid-base interaction between the basic nitrogen adsorbate and the weak acidic support. The Freundlich model was suitable in describing the adsorption of nitrogen- and sulfur-containing compounds from LCO. Cooperative adsorption took place when replacing the model compound DBT by the sulfur-containing compounds in LCO.